Influence of high-energy electron irradiation on the conduction behavior of doped polyaniline films in the high current density regime

被引：12

作者：

Xu, HS ^{[1
]}

Cheng, ZY

Zhang, QM

Wang, PC

MacDiarmid, AG

机构：

[1] Penn State Univ, Mat Res Lab, University Pk, PA 16802 USA

[2] Univ Penn, Dept Chem, Philadelphia, PA 19104 USA

来源：

SYNTHETIC METALS | 2000年 / 108卷 / 02期

关键词：

conducting polymer; polyaniline; high-energy electron irradiation; high current density;

D O I：

10.1016/S0379-6779(99)00184-8

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The influence of high-energy electron irradiation on the conduction behavior at high current density of polyaniline (PANI) films doped with HCl and camphor sulfonic acid (HCSA), respectively, is reported. It is found that there exists an ohmic region under certain current density for both non-irradiated and irradiated samples. No significant change of the conductivity and maximum current density are observed if the sample is irradiated at room temperature and low dosage. The conductivity and maximum current density decrease with dosage if the samples are irradiated at high temperature. However, after redoping with 1 M HCl, the conductivity of these films can be recovered, while the maximum current density remains at a lower level. The DSC thermograms show that the crosslinking density of PANI-HCl film increases due to the high-energy electron irradiation. (C) 2000 Published by Elsevier Science S.A. All rights reserved.

引用

页码：133 / 137

页数：5

共 16 条

[1] POLYANILINE - SOLUTIONS, FILMS AND OXIDATION-STATE [J].

ANGELOPOULOS, M ;

ASTURIAS, GE ;

ERMER, SP ;

RAY, A ;

SCHERR, EM ;

MACDIARMID, AG ;

AKHTAR, M ;

KISS, Z ;

EPSTEIN, AJ .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1988, 160 :151-163

[2] SOLUTION-CAST FILMS OF POLYANILINE - OPTICAL-QUALITY TRANSPARENT ELECTRODES [J].

CAO, Y ;

TREACY, GM ;

SMITH, P ;

HEEGER, AJ .

APPLIED PHYSICS LETTERS, 1992, 60 (22) :2711-2713

[3]

GALLETTI PM, 1988, MED APPL PIEZOELECTR

[4] Porous polyaniline films with high conductivity [J].

Li, WG ;

Wan, MX .

SYNTHETIC METALS, 1998, 92 (02) :121-126

[5] THE CONCEPT OF SECONDARY DOPING AS APPLIED TO POLYANILINE [J].

MACDIARMID, AG ;

EPSTEIN, AJ .

SYNTHETIC METALS, 1994, 65 (2-3) :103-116

[6] SECONDARY DOPING IN POLYANILINE [J].

MACDIARMID, AG ;

EPSTEIN, AJ .

SYNTHETIC METALS, 1995, 69 (1-3) :85-92

[7] TOWARDS OPTIMIZATION OF ELECTRICAL AND MECHANICAL-PROPERTIES OF POLYANILINE - IS CROSS-LINKING BETWEEN CHAINS THE KEY [J].

MACDIARMID, AG ;

MIN, Y ;

WIESINGER, JM ;

OH, EJ ;

SCHERR, EM ;

EPSTEIN, AJ .

SYNTHETIC METALS, 1993, 55 (2-3) :753-760

[8]

Su J, 1998, POLYM ADVAN TECHNOL, V9, P317, DOI 10.1002/(SICI)1099-1581(199806)9:6<317::AID-PAT758>3.3.CO

[9]

2-P

[10]

WEI Y, 1992, POLYMER, V33, P314

← 1 2 →