Fluorescence maxima of 10-methylacridone - Metal ion salt complexes: A convenient and quantitative measure of Lewis acidity of metal ion salts

被引：122

作者：

Fukuzumi, S ^{[1
]}

Ohkubo, K ^{[1
]}

机构：

[1] Osaka Univ, Dept Mat & Life Sci, Grad Sch Engn, CREST,Japan Sci & Technol, Suita, Osaka 5650871, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 35期

关键词：

D O I：

10.1021/ja026613o

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aromatic carbonyl compounds such as 10-methylacridone form the Lewis acid complexes including paramagnetic and redox active Lewis acids. The fluorescence energies of the Lewis acid complexes are well correlated with the O2•--Lewis acid complexes derived from the gzz-values of the ESR spectra of the superoxide anion-Lewis acid complexes, thus providing a quantitative measure of the Lewis acidity. Copyright © 2002 American Chemical Society.

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页码：10270 / 10271

页数：2

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