The analysis of solvation in ionic liquids and organic solvents using the Abraham linear free energy relationship

被引：94

作者：

Acree, William E., Jr.

Abraham, Michael H.

机构：

[1] Univ N Texas, Dept Chem, Denton, TX 76203 USA

[2] UCL, Dept Chem, London WC1H 0AJ, England

来源：

JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY | 2006年 / 81卷 / 08期

关键词：

linear free energy relationship (LFER); solvation equations; ionic liquids; principal component analysis;

D O I：

10.1002/jctb.1589

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

The contentions made in an earlier paper [J Chem Technol Biotechnol 80: 133-137 (200S)] that the coefficients of the Abraham solvation equation do not provide meaningful information on the molecular properties of ionic liquid solvents is refuted. The objections noted in the earlier paper disappear when the solvation equation model is correctly applied to the experimental data. It is further shown that the coefficients of the Abraham solvation equations can be used to characterize ionic liquids and can be used to select solvents for the solubility of gaseous solutes. (c) 2006 Society of Chemical Industry.

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收藏

页码：1441 / 1446

页数：6

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