Synthesis, structure and redox behaviour of gold and silver complexes with 3-ferrocenylpyridine

被引：42

作者：

Barranco, EM

Crespo, O

Gimeno, MC

Jones, PG

Laguna, A ^{[1
]}

Villacampa, MD

机构：

[1] Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, Dept Quim Inorgan, E-50009 Zaragoza, Spain

[2] Tech Univ Carolo Wilhelmina Braunschweig, Inst Anorgan & Analyt Chem, D-38023 Braunschweig, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 592卷 / 02期

关键词：

gold; silver; ferrocene; ferrocenylpyridine; redox behaviour;

D O I：

10.1016/S0022-328X(99)00547-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

3-Ferrocenylpyridine (Fcpy) reacts with gold(I) derivatives to afford neutral, [AuR(Fcpy)] (R = Cl, C6F5), or cationic complexes, [Au(Fcpy)(PPh3)]OTf. Reaction with [Au(C6F5)(2)(OEt2)(2)]ClO4 or [Au(C6F5)(3)(OEt2)] gives the gold(III) complexes [Au(C6F5)(2)(Fcpy)(2)]ClO4 or [Au(C6F5)(3)(Fcpy)], respectively. The silver derivatives [Ag(Fcpy)(PPh3)]OTf and [Ag(OTf)(Fcpy)(2)] have also been synthesised. (C) 1999 Elsevier Science S.A. All rights reserved.

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页码：258 / 264

页数：7

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