Nitrogen-doped open pore channeled graphene facilitating electrochemical performance of TiO2 nanoparticles as an anode material for sodium ion batteries

被引:113
作者
Cha, Hyun Ae [1 ,4 ]
Jeong, Hyung Mo [2 ]
Kang, Jeung Ku [1 ,2 ,3 ]
机构
[1] Korea Adv Inst Sci & Technol, Grad Sch Energy Environm Water & Sustainabil EEWS, Taejon 305701, South Korea
[2] Korea Adv Inst Sci & Technol, Dept Mat Sci & Engn, Taejon 305701, South Korea
[3] Korea Adv Inst Sci & Technol, KAIST Inst Nano Century, Taejon 305701, South Korea
[4] Korea Inst Mat Sci, Powder & Ceram Div, Chang Won 642831, Gyeongnam, South Korea
基金
新加坡国家研究基金会;
关键词
LOW-COST; CARBON; INTERCALATION; NA2TI3O7; STORAGE; CHALLENGES; NANOSHEETS; CAPACITY;
D O I
10.1039/c4ta00041b
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report that titanium dioxide nanoparticles anchored on nitrogen-doped open pore channeled graphene exhibit high performance as anode materials for sodium ion batteries with a high reversible capacity of 405 mA h g(-1) at a current density of 50 mA g(-1), excellent cycle stability with a capacity of 250 mA h g(-1) over 100 charge-discharge cycles at a current density of 100 mA g(-1), and superior rate capability. Also, it shows that high electrochemical performance is attributed to the facilitated ion diffusion by their open pore channels, in addition to the promoted electron transfer in electrochemical reactions by nitrogen-doping.
引用
收藏
页码:5182 / 5186
页数:5
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