Raman scattering and photophysics in spin-state-labile d6 metal complexes

被引：32

作者：

Browne, Wesley R.

McGarvey, John J. ^{[1
]}

机构：

[1] Queens Univ Belfast, Sch Chem & Chem Engn, Belfast BT5 9AG, Antrim, North Ireland

[2] Univ Groningen, NL-9700 AB Groningen, Netherlands

来源：

COORDINATION CHEMISTRY REVIEWS | 2006年 / 250卷 / 13-14期

关键词：

d(6) transition metal ions; DNA-intercalating metal complexes; light-switch effect; resonance Raman scattering; spin-crossover complexes;

D O I：

10.1016/j.ccr.2006.01.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this review two areas of d(6) transition metal ion chemistry and photophysics are briefly reviewed (i) that of Ru(II)dipyridophenazine (dppz) complexes as DNA intercalators and (ii) spin crossover behavior in Fe(II) complexes. In both areas the role of Raman spectroscopy in providing information concerning the spectroscopy and photophysics of the electronic states involved and the interactions between states of differing spin multiplicity is discussed. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：1696 / 1709

页数：14

共 109 条

[1] SYNTHESIS AND STUDY OF A MIXED-LIGAND RUTHENIUM(II) COMPLEX IN ITS GROUND AND EXCITED-STATES - BIS(2,2'-BIPYRIDINE)(DIPYRIDO[3,2-A, 2',3'-C]PHENAZINE-N4N5)RUTHENIUM(II) [J].