Electrodeposition of Polypyrrole/Reduced Graphene Oxide/Iron Oxide Nanocomposite as Supercapacitor Electrode Material

被引:47
作者
Eeu, Y. C. [1 ]
Lim, H. N. [1 ,2 ]
Lim, Y. S. [1 ]
Zakarya, S. A. [1 ]
Huang, N. M. [3 ]
机构
[1] Univ Putra Malaysia, Fac Sci, Dept Chem, Serdang 43400, Selangor, Malaysia
[2] Univ Putra Malaysia, Inst Adv Technol, Funct Device Lab, Serdang 43400, Selangor, Malaysia
[3] Univ Malaya, Fac Sci, Dept Phys, Low Dimens Mat Res Ctr, Kuala Lumpur 50603, Malaysia
关键词
CONDUCTING POLYMERS;
D O I
10.1155/2013/653890
中图分类号
TB3 [工程材料学];
学科分类号
082905 [生物质能源与材料];
摘要
Polypyrrole (PPy) was reinforced with reduced graphene oxide (RGO) and iron oxide to achieve electrochemical stability and enhancement. The ternary nanocomposite film was prepared using a facile one-pot chronoamperometry approach, which is inexpensive and experimentally friendly. The field emission scanning electron microscopy (FESEM) image shows a layered morphology of the ternary nanocomposite film as opposed to the dendritic structure of PPy, suggesting hybridization of the three materials during electrodeposition. X-ray diffraction (XRD) profile shows the presence of Fe2O3 in the ternary nanocomposite. Cyclic voltammetry (CV) analysis illustrates enhanced current for the nanocomposite by twofold and fourfold compared to its binary (PPy/RGO) and individual (PPy) counterparts, respectively. The ternary nanocomposite film exhibited excellent specific capacitance retention even after 200 cycles of charge/discharge.
引用
收藏
页数:6
相关论文
共 22 条
[1]
Multi layered Nanoarchitecture of Graphene Nanosheets and Polypyrrole Nanowires for High Performance Supercapacitor Electrodes [J].
Biswas, Sanjib ;
Drzal, Lawrence T. .
CHEMISTRY OF MATERIALS, 2010, 22 (20) :5667-5671
[2]
Electrochemically synthesized graphene/polypyrrole composites and their use in supercapacitor [J].
Chang, Hao-Hsiang ;
Chang, Chih-Kai ;
Tsai, Yu-Chen ;
Liao, Chien-Shiun .
CARBON, 2012, 50 (06) :2331-2336
[3]
Graphene-Based Flexible Supercapacitors: Pulse-Electropolymerization of Polypyrrole on Free-Standing Graphene Films [J].
Davies, Aaron ;
Audette, Philippe ;
Farrow, Blake ;
Hassan, Fathy ;
Chen, Zhongwei ;
Choi, Ja-Yeon ;
Yu, Aiping .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (35) :17612-17620
[4]
One-step electrochemical composite polymerization of polypyrrole integrated with functionalized graphene/carbon nanotubes nanostructured composite film for electrochemical capacitors [J].
Ding, Bing ;
Lu, Xiangjun ;
Yuan, Changzhou ;
Yang, Sudong ;
Han, Yongqin ;
Zhang, Xiaogang ;
Che, Qian .
ELECTROCHIMICA ACTA, 2012, 62 :132-139
[5]
Functionalized Carbon Nanotube Supercapacitor Electrodes: A Review on Pseudocapacitive Materials [J].
Fisher, Robert A. ;
Watt, Morgan R. ;
Ready, W. Jud .
ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY, 2013, 2 (10) :M3170-M3177
[6]
Simple room-temperature preparation of high-yield large-area graphene oxide [J].
Huang, N. M. ;
Lim, H. N. ;
Chia, C. H. ;
Yarmo, M. A. ;
Muhamad, M. R. .
INTERNATIONAL JOURNAL OF NANOMEDICINE, 2011, 6 :3443-3448
[7]
LIM HN, 2013, ADV TOPICS CRYSTAL G
[8]
Preparation and characterization of polypyrrole/graphene nanocomposite films and their electrochemical performance [J].
Lim, Y. S. ;
Tan, Y. P. ;
Lim, H. N. ;
Huang, N. M. ;
Tan, W. T. .
JOURNAL OF POLYMER RESEARCH, 2013, 20 (06)
[9]
Polypyrrole/Graphene Composite Films Synthesized via Potentiostatic Deposition [J].
Lim, Y. S. ;
Tan, Y. P. ;
Lim, H. N. ;
Tan, W. T. ;
Mahnaz, M. A. ;
Talib, Z. A. ;
Huang, N. M. ;
Kassim, A. ;
Yarmo, M. A. .
JOURNAL OF APPLIED POLYMER SCIENCE, 2013, 128 (01) :224-229
[10]
Lim Y. S., 2013, CERAMICS INT