Dominant role of C-Br•••N halogen bond in molecular self-organization.: Crystallographic and quantum-chemical study of Schiff-base-containing triazoles

被引：42

作者：

Berski, S ^{[1
]}

Ciunik, Z ^{[1
]}

Drabent, K ^{[1
]}

Latajka, Z ^{[1
]}

Panek, J ^{[1
]}

机构：

[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2004年 / 108卷 / 33期

关键词：

D O I：

10.1021/jp049742v

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Three Schiff-base-containing triazole derivatives have been synthesized and investigated by X-ray crystallography. Structural motifs (zigzag or linear chains) formed in the solid state are stabilized by C-Br...N halogen bond interactions, while hydrogen bonds do not seem to play a significant role in the molecular self-organization of studied compounds. Quantum-chemical studies confirm that these interactions are sufficient to account for both the arrangement of structural motifs and very short Br...N distances observed experimentally. It is also shown that Br...N interactions can lead to generally shorter donor-acceptor distances than Cl...N contacts.

引用

页码：12327 / 12332

页数：6

共 43 条

[1] TETRAZOLE STUDIES .2. CRYSTAL-STRUCTURE OF 5-BROMOTETRAZOLE [J].