Fluoroalkylated N-heterocyclic carbene complexes of palladium

被引：89

作者：

Xu, LJ ^{[1
]}

Chen, WP ^{[1
]}

Bickley, JF ^{[1
]}

Steiner, A ^{[1
]}

Xiao, JL ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Leverhulme Ctr Innovat Catalysis, Liverpool L69 7ZD, Merseyside, England

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2000年 / 598卷 / 02期

关键词：

carbenes; fluoroalkylated carbenes; palladium complexes; X-ray structures;

D O I：

10.1016/S0022-328X(00)00008-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Fluoroalkylated N-heterocyclic carbene complexes of palladium have been synthesized from imidazolium salts and Pd(OAc)(2). The analogous carbene complexes bearing long alkyl chains have also been prepared. The formation of these carbene complexes proceeds via an intermediate binuclear species, which has been isolated. Complexes such as these may find applications in catalysis in supercritical CO2 (scCO(2)). (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：409 / 416

页数：8

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