Mn-salen catalyst, competitor of enzymes, for asymmetric epoxidation

被引：356

作者：

Katsuki, T

机构：

[1] Department of Chemistry, Faculty of Science, Kyushu University 33, Fukuoka 812-81, Hakozaki, Higashi-ku

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1996年 / 113卷 / 1-2期

关键词：

(salen)manganese(III) complex; Mn-salen catalyst; oxo transfer reaction; asymmetric epoxidation; simple olefin;

D O I：

10.1016/S1381-1169(96)00106-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Asymmetric epoxidation of simple olefins using (salen)manganese(III) complexes as catalysts has made a great advances in the last half decade and now finds wide application in organic synthesis. In this article; we describe the scope of the reaction, and the principal achievements to date are presented in Tables. The mechanistic aspect of the reaction is also discussed briefly.

引用

页码：87 / 107

页数：21

共 78 条

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