Syntheses and structures of novel heterobimetallic Cu(II)-Au(I) complexes Cu(cyclen)[Au(CN)2]2 and Cu(pyz)[Au(CN)2]2

被引：40

作者：

Yeung, WF

Wong, WT

Zuo, JL

Lau, TC

机构：

[1] City Univ Hong Kong, Dept Biol & Chem, Hong Kong, Hong Kong, Peoples R China

[2] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China

[3] Nanjing Univ, Inst Coordinat Chem, Nanjing 210093, Peoples R China

[4] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 05期

关键词：

D O I：

10.1039/a910350n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel cyano Cu-II-Au-I bimetallic complexes, Cu(cyclen)[Au(CN)(2)](2) 1 (cyclen = 1,4,7,10-tetraazacyclododecane) and Cu(pyz)[Au(CN)(2)](2) 2 (pyz = pyrazine) were prepared; 1 has a dimeric structure arising from Au-I... Au-I interactions, while 2 consists of linear pyrazine-bridged copper chains intercalated to produce a 2-D pleated sheet structure.

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页码：629 / 631

页数：3

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