Determination of low-pressure crystalline-liquid phase boundary of SnI4

被引：24

作者：

Fuchizaki, K ^{[1
]}

Fujii, Y

Ohishi, Y

Ohmura, A

Hamaya, N

Katayama, Y

Okada, T

机构：

[1] Univ Tokyo, ISSP, Neutron Sci Lab, Ibaraki 3191106, Japan

[2] JASRI, SPring 8, Sayo, Hyogo 6795198, Japan

[3] Ochanomizu Univ, Dept Phys, Tokyo 1128610, Japan

[4] JAERI, SPring 8, Sayo, Hyogo 6795148, Japan

[5] Ehime Univ, Dept Phys, Matsuyama, Ehime 7908577, Japan

来源：

JOURNAL OF CHEMICAL PHYSICS | 2004年 / 120卷 / 23期

关键词：

D O I：

10.1063/1.1751397

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The location of the liquidus in the low-pressure crystalline phase of SnI4 was determined utilizing in situ x-ray diffraction measurements under pressures up to approximately 3.5 GPa. The liquidus is not well fitted to a monotonically increasing curve such as Simon's equation, but breaks near 1.5 GPa and then becomes almost flat. The results are compared to those from molecular dynamics simulations. Ways to improve the model potential adopted in the simulations are discussed. (C) 2004 American Institute of Physics.

引用

页码：11196 / 11199

页数：4

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