Morphology and optical properties of MgO thin films on Mo(001)

被引:71
作者
Benedetti, S.
Benia, H. M.
Nilius, N.
Valeri, S.
Freund, H. J.
机构
[1] Max Planck Gesell, Fritz Haber Inst, D-14195 Berlin, Germany
[2] Univ Modena, Dipartimento Fis, I-41100 Modena, Italy
[3] CNR, INFM, Natl Res Ctr NanoStruct & BioSyst Surfaces, I-41100 Modena, Italy
关键词
D O I
10.1016/j.cplett.2006.08.130
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Thin MgO films with a nominal thickness ranging between 1 and 60 ML have been grown on a Mo(001) surface. The film morphology was studied by LEED and STM, revealing the presence of a coincidence pattern with the Mo support in the low coverage regime, a dislocation network at medium thickness and a rather flat and defect-poor MgO surface for thicker layers. The MgO optical properties were investigated as a function of film thickness by analyzing electro-luminescence spectra obtained via electron injection from the STM tip into well-defined surface areas. The spectra are characterized by two distinct emission bands at 3.1 and 4.4 eV. Their origin is discussed in the light of earlier photo-luminescence measurements on MgO nanocubes and smokes. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:330 / 335
页数:6
相关论文
共 33 条
[1]   PHOTOLUMINESCENCE PROPERTIES OF MGO POWDERS WITH COORDINATIVELY UNSATURATED SURFACE IONS [J].
ANPO, M ;
YAMADA, Y ;
KUBOKAWA, Y ;
COLUCCIA, S ;
ZECCHINA, A ;
CHE, M .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1988, 84 :751-764
[2]   Physicochemical and in situ photoluminescence study of the reversible transformation of oxide ions of low coordination into hydroxyl groups upon interaction of water and methanol with MgO [J].
Bailly, ML ;
Costentin, G ;
Lauron-Pernot, H ;
Krafft, JM ;
Che, M .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (06) :2404-2413
[3]   Metal deposits on well-ordered oxide films [J].
Bäumer, M ;
Freund, HJ .
PROGRESS IN SURFACE SCIENCE, 1999, 61 (7-8) :127-198
[4]   Self-organized growth of nanostructure arrays on strain-relief patterns [J].
Brune, H ;
Giovannini, M ;
Bromann, K ;
Kern, K .
NATURE, 1998, 394 (6692) :451-453
[5]   PHOTO-LUMINESCENT SPECTRA OF SURFACE-STATES IN ALKALINE-EARTH OXIDES [J].
COLUCCIA, S ;
DEANE, AM ;
TENCH, AJ .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1978, 74 :2913-2922
[6]   XPS CHARACTERIZATION OF ULTRA-THIN MGO FILMS ON A MO(100) SURFACE [J].
CORNEILLE, JS ;
HE, JW ;
GOODMAN, DW .
SURFACE SCIENCE, 1994, 306 (03) :269-278
[7]   Low-energy electron diffraction investigation of the surface deformation induced by misfit dislocations in thin MgO films grown on Fe(001) [J].
Dynna, M ;
Vassent, JL ;
Marty, A ;
Gilles, B .
JOURNAL OF APPLIED PHYSICS, 1996, 80 (05) :2650-2657
[8]  
ERTL G, 1997, HDB HETEROGENOUS CAT, V4, P2111
[9]   Polar and non-polar domain borders in MgO ultrathin films on Ag(001) [J].
Ferrari, AM ;
Casassa, S ;
Pisani, C ;
Altieri, S ;
Rota, A ;
Valeri, S .
SURFACE SCIENCE, 2005, 588 (1-3) :160-166
[10]   Structure of ultrathin MgO films on Mo(001) [J].
Gallagher, MC ;
Fyfield, MS ;
Bumm, LA ;
Cowin, JP ;
Joyce, SA .
THIN SOLID FILMS, 2003, 445 (01) :90-95