Order-disorder phase transitions of oxygen on Rh(100)

被引:31
作者
Baraldi, A [1 ]
Dhanak, VR [1 ]
Comelli, G [1 ]
Prince, KC [1 ]
Rosei, R [1 ]
机构
[1] UNIV TRIESTE,DIPARTMENTO FIS,I-34127 TRIESTE,ITALY
来源
PHYSICAL REVIEW B | 1997年 / 56卷 / 16期
关键词
D O I
10.1103/PhysRevB.56.10511
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The adsorption and ordering of oxygen atoms on the Rh(100) surface have been investigated by spot profile low-energy electron diffraction measurements as a function of coverage and temperature. Three oxygen induced structures were observed: p(2X2), c(2X2), and (2X2)p4g. Using the intensity and the full width at half maximum of the diffraction spots, the (2x2)p4g-->c(2x2) and c(2X2)-->(1X1) order-disorder phase transitions have been characterized and the phase diagram mapped out. The (2X2)p4g-->c(2X2) transition is assigned to the two-dimensional Ising universality. The role of the adsorbate-adsorbate interactions in the formation of the ordered phases and the kind of defects involved in the order-disorder phase transitions are discussed. [S0163-1829(97)06935-X].
引用
收藏
页码:10511 / 10517
页数:7
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