The isolation and secondary functionalisation of fac-tris-2,2′-bipyridine complexes of ruthenium(II)

被引：34

作者：

Fletcher, NC ^{[1
]}

Nieuwenhuyzen, M ^{[1
]}

Prabarahan, R ^{[1
]}

Wilson, A ^{[1
]}

机构：

[1] Queens Univ Belfast, Sch Chem, Belfast BT9 5AG, Antrim, North Ireland

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 11期

关键词：

D O I：

10.1039/b202886g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

fac-Ruthenium(II) tris-(5-carboxy-2,2'-bipyridine) has been synthesised as a single geometric isomer for the first time, and proves to be a good 'building-block' to introduce new functionality with retention of the isomeric integrity.

引用

页码：1188 / 1189

页数：2

共 12 条

[1] A monometallic and kinetically inert complex of a ditopic open ligand as a tight polyaza cage [J].

Amendola, V ;

Fabbrizzi, L ;

Mangano, C ;

Lanfredi, AM ;

Pallavicini, P ;

Perotti, A ;

Ugozzoli, F .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (07) :1155-1160

[2] Luminescent and redox-active polynuclear transition metal complexes [J].

Balzani, V ;

Juris, A ;

Venturi, M ;

Campagna, S ;

Serroni, S .

CHEMICAL REVIEWS, 1996, 96 (02) :759-833

[3] RUTHENIUM(II)-POLYPYRIDINE CAGE COMPLEXES - LUMINESCENCE AND PHOTOCHEMICAL PROPERTIES [J].

DECOLA, L ;

BARIGELLETTI, F ;

BALZANI, V ;

BELSER, P ;

VONZELEWSKY, A ;

VOGTLE, F ;

EBMEYER, F ;

GRAMMENUDI, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (21) :7210-7212

[4] The isolation and purification of tris-2,2′-bipyridine complexes of ruthenium(II) containing unsymmetrical ligands [J].

Fletcher, NC ;

Nieuwenhuyzen, M ;

Rainey, S .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (18) :2641-2648

[5] Comparison of the rates and mechanisms of formation and solvolysis of [Fe(bipy)3]2+ (bipy = 2,2′-bipyridine) and [FeL]2+ [L = 1,4,7-tris(2,2′-bipyridyl-5-ylmethyl)-1,4,7-triazacyclononane] and their stabilities in dimethylformamide solution [J].

Josceanu, AM ;

Moore, P .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (03) :369-374

[6] RU(II) POLYPYRIDINE COMPLEXES - PHOTOPHYSICS, PHOTOCHEMISTRY, ELECTROCHEMISTRY, AND CHEMI-LUMINESCENCE [J].

JURIS, A ;

BALZANI, V ;

BARIGELLETTI, F ;

CAMPAGNA, S ;

BELSER, P ;

VONZELEWSKY, A .

COORDINATION CHEMISTRY REVIEWS, 1988, 84 :85-277

[7] Luminescent sensor molecules based on coordinated metals: a review of recent developments [J].

Keefe, MH ;

Benkstein, KD ;

Hupp, JT .

COORDINATION CHEMISTRY REVIEWS, 2000, 205 :201-228

[8] Stereochemistry and polymetallic ligand-bridged molecular assemblies [J].

Keene, FR .

COORDINATION CHEMISTRY REVIEWS, 1997, 166 :121-159

[9]

Keene FR, 1998, CHEM SOC REV, V27, P185

[10]

SHELDON P, 1994, CHEM COMMUN, P2489

← 1 2 →