Fabrication of CdS/TiO2 nano-bulk composite photocatalysts for hydrogen production from aqueous H2S solution under visible light

被引：165

作者：

Jang, Jum Suk

Li, Wei

Oh, Se Hyuk

Lee, Jae Sung

机构：

[1] Pohang Univ Sci & Technol, Dept Chem Engn, Pohang 790784, Gyungbuk, South Korea

[2] Pohang Univ Sci & Technol, Sch Environm Sci & Engn, Pohang 790784, Gyungbuk, South Korea

[3] GM Corp, R&D Ctr, Warren, MI 48090 USA

来源：

CHEMICAL PHYSICS LETTERS | 2006年 / 425卷 / 4-6期

关键词：

D O I：

10.1016/j.cplett.2006.05.031

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 [物理化学]; 081704 [应用化学];

摘要：

CdS/TiO2 nano-bulk composite (NBC) photocatalyst of a new configuration consisting of bulky CdS with high crystallinity decorated with nanosized TiO2 particles exhibited an unprecedented high rate of hydrogen production under visible light irradiation (lambda >= 420 nm) from water containing sulfide and sulfite ions as hole scavengers. The fabrication method of the composite photocatalysts was critical for their performance. It was demonstrated that this active composite photocatalyst could be applied for practical processes of simultaneous hydrogen production and H2S removal in the treatment of Claus plant tail gas streams or vents of hydrodesulfurization plants. (c) 2006 Elsevier B.V. All rights reserved.

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页码：278 / 282

页数：5

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