Hydrogen production by ethanol reforming over NiZnAl catalysts

被引：88

作者：

Barroso, M. Noelia ^{[1
]}

Gomez, Manuel F. ^{[1
]}

Arrua, Luis A. ^{[1
]}

Abello, M. Cristina ^{[1
]}

机构：

[1] Consejo Nacl Invest Cient & Tecn, UNSL, Inst Invest & Tecnol Quim, RA-5700 San Luis, Argentina

来源：

APPLIED CATALYSIS A-GENERAL | 2006年 / 304卷 / 01期

关键词：

ethanol; steam reforming; hydrogen production; NiZnAl catalysts;

D O I：

10.1016/j.apcata.2006.02.033

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

NiZnAl catalysts with different Ni loading (1-25 wt.%) and a Zn:Al atomic ratio nearly constant (Zn:Al congruent to 0.6) were prepared by the citrate sol gel method and characterized by different techniques such as TG, BET, TPR, XRD and Fr-IR. They were active in the ethanol steam reforming at atmospheric pressure in the temperature range 500-600 degrees C. However, there were significant differences in their performance. On catalysts with high Ni loading (18-25 wt.%) high hydrogen selectivities around 85% were obtained. CO, CO2 and small amount of CH4 were the only by-products at 600 degrees C. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：116 / 123

页数：8

共 27 条

[1] Synthesis, characterization and performance evaluation of Ni/Al2O3 catalysts for reforming of crude ethanol for hydrogen production [J].