N2O oxidation of phosphines catalyzed by low-valent nickel complexes

被引：28

作者：

Yamada, T ^{[1
]}

Suzuki, K ^{[1
]}

Hashimoto, K ^{[1
]}

Ikeno, T ^{[1
]}

机构：

[1] Keio Univ, Fac Sci & Technol, Dept Chem, Kohoku Ku, Yokohama, Kanagawa 2238522, Japan

来源：

CHEMISTRY LETTERS | 1999年 / 10期

关键词：

D O I：

10.1246/cl.1999.1043

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of a catalytic amount of the nickel(0). complex derived from Ni(acac)(2) or NiCl2 with DIBAL or BuLi, nitrous oxide (N2O) was captured and activated to oxidize phosphine(III) into the corresponding phosphine oxide. Bidentate phosphines, for example, 1,3-bis(diphenylphosphino)propane (dppp), were employed as effective ligands for N2O oxidation and were recovered after the reaction.

引用

页码：1043 / 1044

页数：2

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