Unusual geometries in main group chemistry

被引：51

作者：

Bouhadir, G ^{[1
]}

Bourissou, D ^{[1
]}

机构：

[1] Univ Toulouse 3, CNRS, UMR 5069, Lab Heterochim Fondamentale & Appl, F-31062 Toulouse 04, France

来源：

CHEMICAL SOCIETY REVIEWS | 2004年 / 33卷 / 04期

关键词：

D O I：

10.1039/b306615k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Over the past twenty five years, numerous heteroatom-containing analogues of classical organic moieties have been prepared and structurally characterized. The incorporation of group 13 to 15 heteroelements has often been reported to induce significant geometric distortions compared to the corresponding carbon compounds. These unusual geometries in main group derivatives are examined in this tutorial review, and the precise role of the heteroelements is discussed.

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页码：210 / 217

页数：8

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