A direct conversion of α,β-unsaturated ketones to vinylcyclopropanes:: new zirconium-mediated reaction

被引：18

作者：

Bertus, P ^{[1
]}

Gandon, V ^{[1
]}

Szymoniak, J ^{[1
]}

机构：

[1] Univ Reims, F-51687 Reims 2, France

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 02期

关键词：

D O I：

10.1039/a908897k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Various vinylcyclopropanes are synthesized from alpha,beta-unsaturated ketones via a zirconium-mediated [1,2]-addition-deoxygenative cyclopropanation sequence; the latter step surprisingly proceeds under specific protic conditions.

引用

页码：171 / 172

页数：2

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