'Zur Lehre von der Wirkung der Salze' (about the science of the effect of salts): Franz Hofmeister's historical papers

被引:861
作者
Kunz, W [1 ]
Henle, J [1 ]
Ninham, BW [1 ]
机构
[1] Univ Regensburg, Inst Phys & Theoret Chem, D-93040 Regensburg, Germany
关键词
Franz Hofmeister; salt effects; electrolytes; protein precipitation; colloids; ion-water interactions;
D O I
10.1016/j.cocis.2004.05.005
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Specific ion effects are universal in biology, biochemistry, chemistry and chemical engineering. In a seminal series of papers, Franz Hofmeister, Professor of Pharmacology at the University of Prague was the first to study these effects systematically. His work stands in the scheme of things in importance much as did the work of Mendel to genetics. For over a hundred years Hofmeister effects have not been encompassed by theories of solution or colloid chemistry. It is only recently, the subject of this special issue, that some progress has been made. Hofmeister's work is much quoted. But practically no one has ever actually read his papers (originals in archaic German). They are model scientific works for their, and indeed for our time. This article gives translations of two of his most important contributions. (C) 2004 Elsevier Ltd. All rights reserved.
引用
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页码:19 / 37
页数:19
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