Low frequency Raman active vibrations in fullerenes. 1. Monopolar modes

被引：33

作者：

Eisler, HJ ^{[1
]}

Gilb, S ^{[1
]}

Hennrich, FH ^{[1
]}

Kappes, MM ^{[1
]}

机构：

[1] Univ Karlsruhe, Inst Chem Phys, D-76128 Karlsruhe, Germany

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 2000年 / 104卷 / 08期

关键词：

D O I：

10.1021/jp9932665

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Raman measurements and PM3 calculations of low frequency (<600 cm(-)) vibrational modes in a variety of different, fullerenes can be rationalized in terms of the multipolar "acoustic'' oscillations of isotropic spherical and spheroidal shells. In this first of a two part series, we show that all fullerene cages have monopolar-like breathing vibrations. Within certain boundary conditions and in the absence of other data, the frequency of these vibrations may be used for cage size determination.

引用

页码：1762 / 1768

页数：7

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