Hyperbranched polyesters based on adipic acid and glycerol

被引:121
作者
Stumbé, JF [1 ]
Bruchmann, B [1 ]
机构
[1] BASF AG, Polymer Res, D-67056 Ludwigshafen, Germany
关键词
adipic acid; degree of branching; glycerol; hyperbranched polymers; NMR; polyesters; SEC;
D O I
10.1002/marc.200300298
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Hyperbranched polyesters with controlled molecular weights and properties have been prepared by an A(2) + B-3 approach by reacting glycerol and adipic acid without any solvents in the presence of tin catalysts. The hyper-branched polyesters have been evaluated by size exclusion chromatography (SEC) analysis and NMR spectroscopy in order to determine molecular weights and degrees of branching.
引用
收藏
页码:921 / 924
页数:4
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