Effects of surface modification on the electrochemical performance of pyrolyzed sugar carbons as anode materials for lithium-ion batteries

被引:32
作者
Fey, GTK [1 ]
Chen, KL
Chang, YC
机构
[1] Natl Cent Univ, Dept Chem Engn, Chungli 320, Taiwan
[2] Tamkang Univ, Dept Chem Engn, Tamsui 251, Taiwan
关键词
surface modification; sugar; carbon; anode materials; H2O2; HNO3; H2SO4; lithium-ion batteries;
D O I
10.1016/S0254-0584(01)00495-3
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The surface of pyrolyzed sugar carbons (PSCs) was treated with H2O2, HNO3, or H2SO4 reagents. Surface modification of these materials improved their electrode performance. FTIR, Raman, C-13 NMR, and X-ray diffraction (XRD) spectroscopic techniques were used to characterize structures of the treated and untreated carbons. The charge/discharge capacity, potential profile, and irreversible capacity loss have been investigated. The correlations between cell capacities, H/C ratios, and Raman vibrational modes are discussed. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:1 / 6
页数:6
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