Ag(I) complexes generated from double Schiff-base ligand with thiazole as the terminal binding sites

被引：52

作者：

Dong, Yu-Bin ^{[1
]}

Wang, Le ^{[1
]}

Ma, Jian-Ping ^{[1
]}

Zhao, Xia-Xia ^{[1
]}

Shen, Da-Zhong ^{[1
]}

Huang, Ru-Qi ^{[1
]}

机构：

[1] Shandong Normal Univ, Shandong Key Lab Funct Chem Mat, Coll Chem Chem Engn & Mat Sci, Jinan 250014, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2006年 / 6卷 / 11期

关键词：

D O I：

10.1021/cg060158g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A double Schiff-base ligand 1,4-bis(2-thiazolyl)-2,3-diaza-1,3-butadiene (L8) has been synthesized, and its coordination chemistry with various silver salts AgX (X = SbF6-, SO3CF3-, H2PO4-, and NO3-) has been investigated. The resulting molecular structures are delicately dependent on the nature of the counterions and the solvent intermedia. Uncoordinating counterions (X = SbF6- and SO3CF3-) generated the hydrogen-bonded frameworks based on discrete molecular complex building blocks, whereas coordinating anions (X = H2PO4- and NO3-) formed polymeric complexes driven by the metal-anion interactions. Furthermore, the luminescent and electrical conductive properties of some new complexes were investigated.

引用

页码：2475 / 2485

页数：11

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