The topochemical 1,16-polymerization of a triene

被引:93
作者
Hoang, T [1 ]
Lauher, JW [1 ]
Fowler, FW [1 ]
机构
[1] SUNY Stony Brook, Dept Chem, Stony Brook, NY 11794 USA
关键词
D O I
10.1021/ja027444a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The first topochemical 1,6-polymerization of a triene has been observed. The required supramolecular structure for this polymerization was achieved by the π-π stacking of the isonicotinate functionality. The crystal environment of this polymerization reaction controlled both the molecular and supramolecular structure of the polymer and allowed its structure to be determined by single-crystal X-ray diffraction. Copyright © 2002 American Chemical Society.
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页码:10656 / 10657
页数:2
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