Structural FTIR analysis and thermal characterisation of lyocell and viscose-type fibres

被引:555
作者
Carrillo, A
Colom, X
Sunol, JJ
Saurina, J
机构
[1] UPC, EUETIT, Dept Chem Engn, Terrassa 08222, Spain
[2] Univ Girona, Dept Phys, Girona 17071, Spain
关键词
lyocell; cellulose; infrared (IR) spectroscopy; calorimetry; thermogravimetry;
D O I
10.1016/j.eurpolmj.2004.05.003
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The microstructure and thermal properties of lyocell and other regenerated cellulose fibres (viscose and modal) were analysed using DSC, TG and FTIR. The FTIR spectral analysis showed that lyocell is the most crystalline fibre and is composed principally of crystalline cellulose II and amorphous cellulose. Likewise, the thermal analysis showed that lyocell has a higher thermal stability than viscose and modal fibres, as the difference between the onset temperature for its decomposition process was as high as 20 degreesC. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2229 / 2234
页数:6
相关论文
共 23 条
[1]  
BOCHEK AM, 1995, CELLULOSE CELLULOSE, P131
[2]   Structural characterization and properties of lyocell fibers after fibrillation and enzymatic defibrillation finishing treatments [J].
Carrillo, F ;
Colom, X ;
Valldeperas, J ;
Evans, D ;
Huson, M ;
Church, J .
TEXTILE RESEARCH JOURNAL, 2003, 73 (11) :1024-1030
[3]   PRODUCTION OF REGENERATED CELLULOSE FIBERS WITHOUT CARBON-DISULFIDE [J].
CHEGOLYA, AS ;
GRINSHPAN, DD ;
BURD, EZ .
TEXTILE RESEARCH JOURNAL, 1989, 59 (09) :501-506
[4]   Structural analysis of photodegraded wood by means of FTIR spectroscopy [J].
Colom, X ;
Carrillo, F ;
Nogués, F ;
Garriga, P .
POLYMER DEGRADATION AND STABILITY, 2003, 80 (03) :543-549
[5]   Crystallinity changes in lyocell and viscose-type fibres by caustic treatment [J].
Colom, X ;
Carrillo, F .
EUROPEAN POLYMER JOURNAL, 2002, 38 (11) :2225-2230
[6]   Structure of regenerated cellulose fibers from DMAc/LiCl solution [J].
Hong, YK ;
Chung, KH ;
Lee, WS .
TEXTILE RESEARCH JOURNAL, 1998, 68 (01) :65-69
[7]  
*ISO, 1999, 20761999 ISO
[8]   COMPARATIVE CHARACTERIZATION OF SOLVENT SPUN CELLULOSE AND HIGH WET MODULUS VISCOSE FIBERS BY THEIR LONG PERIODS [J].
LENZ, J ;
SCHURZ, J ;
WRENTSCHUR, E .
ACTA POLYMERICA, 1992, 43 (06) :307-312
[9]   THE FIBRILLAR STRUCTURE OF CELLULOSIC MAN-MADE FIBERS SPUN FROM DIFFERENT SOLVENT SYSTEMS [J].
LENZ, J ;
SCHURZ, J ;
WRENTSCHUR, E .
JOURNAL OF APPLIED POLYMER SCIENCE, 1988, 35 (08) :1987-2000
[10]  
Lenz J, 1994, Lenzinger Berichte, V74, P19