Preparation and reactivity of 1,3,5,7-tetrakis[4-(diacetoxyiodo)phenyl]adamantane, a recyclable hypervalent iodine(III) reagent

被引：90

作者：

Tohma, H

Maruyama, A

Maeda, A

Maegawa, T

Dohi, T

Shiro, M

Morita, T

Kita, Y

机构：

[1] Osaka Univ, Grad Sch Pharmaceut Sci, Suita, Osaka 5650871, Japan

[2] Rigaku Corp, Akishima, Tokyo 1968666, Japan

[3] JEOL Ltd, Grp Analyt Instruments Div 2, Akishima, Tokyo 1968558, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 27期

关键词：

green chemistry; hypervalent compounds; iodine; oxidation; synthetic methods;

D O I：

10.1002/anie.200454234

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A wide range of oxidative reactions are mediated by novel, nonpolymeric, and recyclable hypervalent IIII reagents (e.g. 2). In all cases, tetraiodide 1 was recovered nearly quantitatively in pure form after a simple workup. Reoxidation of 1 to 2 with m-chloroperbenzoic acid also proceeded quantitatively, without loss of oxidative activity.

引用

页码：3595 / 3598

页数：4

共 46 条

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