The hydrogen bonded polymer structures of [{Mn(2-mbiH)2•TMEDA}•A-A]∞ [2-mbiH2=2-mercaptobenzimidazole;: A-A = TMEDA (Me2NCH2CH2NMe2) or DABCO (N{CH2CH2}3N)]

被引：7

作者：

Beswick, MA ^{[1
]}

Mosquera, MEG ^{[1
]}

Palmer, JS ^{[1
]}

Raithby, PR ^{[1
]}

Wright, DS ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

NEW JOURNAL OF CHEMISTRY | 1999年 / 23卷 / 10期

关键词：

D O I：

10.1039/a809066a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of [MnCp2] with 2-mbiH(2) (1 : 2 equiv.) in the presence of TMEDA gives [{Mn(2-mbiH)(2). TMEDA}. TMEDA](infinity) 1. A similar reaction employing TMEDA and DABCO (1 :1 equiv.) yields [{Mn(2-mbiH)(2). TMEDA}. DABCO](infinity) 2. In the crystal, both complexes adopt similar polymeric structures in which the bifunctional [Mn(2-mbiH)(2). TMEDA] units are associated by hydrogen bonds to lattice-bound TMEDA or DABCO ligands. The structural motif adopted by both complexes can be regarded as resulting from a fusion of separate helical elements.

引用

页码：1033 / 1039

页数：7

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