Synthesis and structures of paramagnetic organo titanium fluoride clusters

被引：13

作者：

Liu, FQ ^{[1
]}

Kunzel, A ^{[1
]}

Herzog, A ^{[1
]}

Roesky, HW ^{[1
]}

Noltemeyer, M ^{[1
]}

Fleischer, R ^{[1
]}

Stalke, D ^{[1
]}

机构：

[1] UNIV WURZBURG,INST ANORGAN CHEM,D-97074 WURZBURG,GERMANY

来源：

POLYHEDRON | 1997年 / 16卷 / 01期

关键词：

organometallic; titanium; cluster; fluoride;

D O I：

10.1016/0277-5387(96)00268-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The organo titanium(IV)trifluoride [C5H4(SiMe(3))]TiF3, 2, has been reduced with zinc and manganese, respectively. As an intermediate product from these reactions the tetra-nuclear Ti-III cluster {[C5H4 (SiMe(3))]2TiF2}Ti-3, 3, has been obtained. By oxidative fluorination using AgF complex 3 was converted to the titanium(IV) complex [C5H4(SiMe(3))]2TiF2. Reduction of (C5H5)(2)TiF2 with gallium led to the formation of [(C5H5)(2)TiF2]Ga-3, 7. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：61 / 65

页数：5

共 17 条

[1] HEXAKIS(MU-3-THIO)PENTAKIS[(ETA-5-CYCLOPENTADIENYL)-TITANIUM], [(ETA-5-C5H5)TI)5(MU-3-S)6] - PREPARATION AND MOLECULAR AND ELECTRONIC-STRUCTURE [J].

BOTTOMLEY, F ;

EGHAREVBA, GO ;

WHITE, PS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (14) :4353-4354

[2] REACTIONS OF BIS(CYCLOPENTADIENYL)TITANIUM AND BIS(PENTAMETHYLCYCLOPENTADIENYL)TITANIUM AND BIS(CYCLOPENTADIENYL)TITANIUM AND BIS(PENTAMETHYLCYCLOPENTADIENYL)ZIRCONIUM DICARBONYLS WITH WATER AND DIHYDROGEN SULFIDE - EVOLUTION OF DIHYDROGEN AND FORMATION OF OXO OR SULFIDO MONOMERS, DIMERS, OR CLUSTERS [J].

BOTTOMLEY, F ;

DRUMMOND, DF ;

EGHAREVBA, GO ;

WHITE, PS .

ORGANOMETALLICS, 1986, 5 (08) :1620-1625

[3] FASTER DATA-COLLECTION WITHOUT LOSS OF PRECISION - AN EXTENSION OF THE LEARNT PROFILE METHOD [J].

CLEGG, W .

ACTA CRYSTALLOGRAPHICA SECTION A, 1981, 37 (JAN) :22-28

[4] TRIMETHYLTIN FLUORIDE - A NEW FLUORINATING REAGENT FOR THE PREPARATION OF ORGANOMETALLIC FLUORIDES [J].

HERZOG, A ;

LIU, FQ ;

ROESKY, HW ;

DEMSAR, A ;

KELLER, K ;

NOLTEMEYER, M ;

PAUER, F .

ORGANOMETALLICS, 1994, 13 (04) :1251-1256

[5] HOMOGENEOUS HYDROGENATION OF CARBON-MONOXIDE [J].

HUFFMAN, JC ;

STONE, JG ;

KRUSELL, WC ;

CAULTON, KG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (17) :5829-5831

[6]

KOPF H, 1982, CHEM SCRIPTA, V19, P122

[7] CRYSTAL HANDLING AT LOW-TEMPERATURES [J].

KOTTKE, T ;

STALKE, D .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1993, 26 :615-619

[8] (C(5)ME(5))TIF2 - A VERSATILE BUILDING-BLOCK FOR GENERATING LARGE SOLUBLE DIMETALLIC AGGREGATES [J].

LIU, FQ ;

STALKE, D ;

ROESKY, HW .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (17) :1872-1874

[9] MOLECULAR-SOLIDS AS LIGANDS IN ORGANOMETALLIC CHEMISTRY - [CP(6)(ASTERISK)TI(6)NA(7)F(19)CENTER-DOT-2.5THF] (CP(ASTERISK)=C(5)ME(5)) AND [CP(4)(ASTERISK)TI(4)MG(2)F(12)CENTER-DOT-7THF], LINKS BETWEEN IONIC SOLIDS AND ORGANOMETALLIC COMPOUNDS [J].

LIU, FQ ;

KUHN, A ;

HERBSTIRMER, R ;

STALKE, D ;

ROESKY, HW .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (05) :555-556

[10]

LIU FQ, 1993, ANGEW CHEM INT EDIT, V32, P441

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