Chemistry of M(allyl)3 (M = Rh, Ir) compounds:: structural characterization of tris(allyl)iridium complexes with phosphorus ligands

被引：22

作者：

John, KD

Salazar, KV

Scott, BL

Baker, RT

Sattelberger, AP

机构：

[1] Univ Calif Los Alamos Natl Lab, Los Alamos Catalysis Initiat Chem Sci & Technol D, Los Alamos, NM 87545 USA

[2] Univ Calif Los Alamos Natl Lab, Div Mat Sci & Technol, Los Alamos, NM 87545 USA

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 07期

关键词：

D O I：

10.1039/a910164k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

While addition of phosphorus ligands such as P(OPh)(3) to Rh(allyl)(3) gives monovalent Rh(allyl)L-2, the iridium analog gives stable mixed sigma/pi-tris(allyl) complexes, as evidenced by the structural characterization of mono-, bi-, and tri-dentate ligand complexes.

引用

页码：581 / 582

页数：2

共 14 条

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