Adsorption of Cr(III) and Fe(III) on an inorganic-organic silicon hybrid surface

被引:9
作者
de Farias, RF
de Souza, AG
Nunes, LM
Cardoso, VD
机构
[1] Univ Fed Roraima, Dept Quim, BR-69301970 Boa Vista, Roraima, Brazil
[2] Univ Fed Paraiba, Dept Quim, BR-58059900 Joao Pessoa, Paraiba, Brazil
关键词
sol-gel; hybrids; adsorption; chromium; iron;
D O I
10.1016/S0927-7757(02)00241-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
By using tetraethylortosilicate (TEOS) and n-[3(trimethoxysilyl) propyl]-ethylenediamine, a silicon inorganic-organic hybrid matrix with 4.0 mmol g(-1) of pendant organic moiety was synthesized. The hybrid matrix was used as a substrate for the adsorption of chromium and iron from their chloride aqueous solutions. The matrix shows a higher affinity towards chromium, with concentrated iron solutions provoking its dissolution. The maximum adsorption capacity towards chromium and iron was 0.56 and 0.38 mmol g(-1), respectively. (C) 2002 Published by Elsevier Science B.V.
引用
收藏
页码:295 / 298
页数:4
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