Analysis of petroleum resins using electrospray ionization tandem mass spectrometry

被引：29

作者：

Porter, DJ

Mayer, PM ^{[1
]}

Fingas, M

机构：

[1] Univ Ottawa, Dept Chem, Ottawa, ON K1N 6N5, Canada

[2] Environm Canada, Environm Protect Serv, Emergencies Sci & Technol Div, Ottawa, ON K1A 0H3, Canada

来源：

ENERGY & FUELS | 2004年 / 18卷 / 04期

关键词：

D O I：

10.1021/ef0340099

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Electrospray ionization mass spectrometry (ESI-MS) is becoming a common method for the analysis of petroleum-based chemicals. Here, we have demonstrated the usefulness of this method for the analysis of polar resin fractions of crude oil, fuel oil, and diesel. The mass spectra of crude oil resins can be used to make comparisons between the constituents present in these oils. Tandem mass spectra of one crude oil sample identified a major constituent to be alkylated carbazoles. The analysis of resins from a diesel sample showed the presence of quinoline compounds, along with oxygen or sulfur heterocycles and alkyl carbazoles. The effect of weathering on the composition of petroleum resins was studied by comparing the average number molecular weights generated from mass spectra.

引用

页码：987 / 994

页数：8

共 22 条

[1]

Ali M. F., 1989, Fuel Science and Technology International, V7, P1179, DOI DOI 10.1080/08843758908962284

[2] Subfractionation, characterization and photooxidation of crude oil resins [J].

Boukir, A ;

Aries, E ;

Guiliano, M ;

Asia, L ;

Doumenq, P ;

Mille, G .

CHEMOSPHERE, 2001, 43 (03) :279-286

[3]

BUCHANAN M, 1982, ANAL CHEM, V54, P571

[4]

*ENV CAN, 2002, DRAFT METH SIM WEATH

[5]

*ENV CAN, 2002, CONST OIL PETR PROD

[6]

Gough MA, 1999, RAPID COMMUN MASS SP, V13, P227, DOI 10.1002/(SICI)1097-0231(19990228)13:4<227::AID-RCM442>3.0.CO

[7]

2-D

[8] SEPARATION AND IDENTIFICATION BY GAS-CHROMATOGRAPHY AND GAS-CHROMATOGRAPHY MASS-SPECTROMETRY OF THE NITROGEN-COMPOUNDS FROM A DEASPHALTED HEAVY OIL - EVOLUTION OF THEIR DISTRIBUTION AFTER A CATALYTIC HYDROTREATMENT [J].

IGNATIADIS, I ;

SCHMITTER, JM ;

ARPINO, P .

JOURNAL OF CHROMATOGRAPHY, 1985, 324 (01) :87-111

[9] Role of asphaltene and resin in oil field emulsions [J].

Khadim, MA ;

Sarbar, MA .

JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING, 1999, 23 (3-4) :213-221

[10]

KHATTAB SA, 1978, EGYPT J CHEM, V21, P421

← 1 2 3 →