New approach to determination of the surface phase capacity in liquid adsorption on the homogeneous solid surfaces

被引：9

作者：

Dabrowski, A

Podkoscielny, P

机构：

[1] Department of Theoretical Chemistry, Faculty of Chemistry, Maria Curie-Słodowska Univ.

来源：

LANGMUIR | 1997年 / 13卷 / 13期

关键词：

D O I：

10.1021/la9700634

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Theoretical foundations are presented to analyze the errors resulting from the determination of the surface phase capacity from the excess isotherms at the solid-liquid interface. It is shown that this analysis provides the answer to the question whether the reliable results are obtained within the assumed adsorption models. Several experimental systems are analyzed to illustrate the usefulness of the presented approach.

引用

页码：3464 / 3473

页数：10

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