Oxidation of primary and secondary alcohols catalyzed by a pentamethylcyclopentadienyliridium complex

被引：92

作者：

Fujita, K ^{[1
]}

Furukawa, S

Yamaguchi, R

机构：

[1] Kyoto Univ, Fac Integrated Human Studies, Dept Nat & Environm Sci, Kyoto 6068501, Japan

[2] Kyoto Univ, Grad Sch Human & Environm Studies, Kyoto 6068501, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 649卷 / 02期

关键词：

iridium catalyst; pentamethylcyclopentadienyl complex; oxidation; hydrogen transfer;

D O I：

10.1016/S0022-328X(01)01461-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The oxidation of primary and secondary alcohols is carried out in acetone under mild conditions using catalytic amounts of [Cp*IrCl2](2) and K2CO3. Primary alcohols are converted into the corresponding aldehydes with high selectivity in good yields. Secondary alcohols are readily oxidized to ketones with smaller amounts of the catalyst. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：289 / 292

页数：4

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