Modelling of the thermodnyamic properties of the ammonia/water mixture

被引:17
作者
Barhoumi, M [1 ]
Snoussi, A [1 ]
Ben Ezzine, N [1 ]
Mejbri, K [1 ]
Bellagi, A [1 ]
机构
[1] Ecole Natl Ingn Monastir, Unite Rech Therm & Thermodynam Procedes Ind, Monastir, Tunisia
来源
INTERNATIONAL JOURNAL OF REFRIGERATION-REVUE INTERNATIONALE DU FROID | 2004年 / 27卷 / 03期
关键词
modelling; thermodynamic properties; mixture; ammonia; water; adsorption system;
D O I
10.1016/j.ijrefrig.2003.09.005
中图分类号
O414.1 [热力学];
学科分类号
摘要
The present work deals with the modeling of the thermodynamic properties of the ammonia/water mixture using the Gibbs free energy function. For the liquid phase, a three constant Margules model of the excess free enthalpy is formulated perfect mixture of real gases, each pure gas being described by a virial equation state The vapour phase is considered as a per in pressure truncated after the third term. The model developed describes with a good accuracy v the mixture in the three states, subcooled liquid, superheated vapour and liquid-vapour saturation,for temperatures from 200 to 500 K and pressures up to 100 bar. (C) 2003 Elsevier Ltd and IIR. All rights reserved.
引用
收藏
页码:271 / 283
页数:13
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