Ruthenium(II) ammine centres as efficient electron donor groups for quadratic non-linear optics

被引：50

作者：

Coe, BJ

EssexLopresti, JP

Harris, JA

Houbrechts, S

Persoons, A

机构：

[1] UNIV LEUVEN,CTR RES MOL ELECT & PHOTON,LAB CHEM & BIOL DYNAM,B-3001 LOUVAIN,BELGIUM

[2] UNIV ARIZONA,CTR OPT SCI,TUCSON,AZ 85721

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 17期

关键词：

D O I：

10.1039/a702681a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ruthenium(II) complex salts trans-[Ru(NH3)(4)(L-D)- (L-A)][PF6](3) (L-D = an N-donor ligand, L-A = a 4,4'-bipyridinium ligand) exhibit large, tunable static first hyperpolarizabilities beta(o) which are associated with intense, visible metal-to-ligand charge-transfer excitations.

引用

页码：1645 / 1646

页数：2

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