Hybrid molecular materials having conducting and magnetic networks: Charge transfer salts based on organic pi-donor molecules and inorganic magnetic clusters.

被引:22
作者
Coronado, E [1 ]
Delhaes, P [1 ]
GalanMascaros, JR [1 ]
GimenezSaiz, C [1 ]
GomezGarcia, CJ [1 ]
机构
[1] CNRS,CTR RECH PAUL PASCAL,F-33600 PESSAC,FRANCE
关键词
magnetic measurements; conductivity; organic conductors based on radical cations; polypyrrole; molecule-based magnets; organic/inorganic structures;
D O I
10.1016/S0379-6779(97)80382-7
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The synthesis and physical characterization of new organic-inorganic hybrids formed by conducting and magnetic networks are reported. The crystalline radical salts are formed by BEDT-TTF type donors as conducting component, and by large metaloxide clusters of variable sizes and shapes (polyoxometalates) as magnetic component. We also show how these magnetic clusters can be incorporated in conducting organic polymers to give hybrid organic/inorganic films.
引用
收藏
页码:1647 / 1650
页数:4
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