Solvation of palladium diacetate in trifluoroacetic acid

被引：18

作者：

Swang, O ^{[1
]}

Blom, R ^{[1
]}

Ryan, OB ^{[1
]}

Faegri, K ^{[1
]}

机构：

[1] UNIV OSLO,DEPT CHEM,N-0315 OSLO,NORWAY

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1996年 / 100卷 / 43期

关键词：

D O I：

10.1021/jp9621944

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The solvation of palladium diacetate in trifluoroacetic acid has been studied by ab initio quantum chemical calculations and infrared and NMR spectroscopy. We report evidence for the formation of a dicarboxylate-dicarboxylic acid species, with square planar coordination around the metal center, through addition of two acid molecules.

引用

页码：17334 / 17336

页数：3

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