Expanding the LnZ3/alkali-metal reduction system to organometallic and heteroleptic precursors:: Formation of dinitrogen derivatives of lanthanum

被引：71

作者：

Evans, WJ ^{[1
]}

Lee, DS ^{[1
]}

Lie, C ^{[1
]}

Ziller, JW ^{[1
]}

机构：

[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 41期

关键词：

alkali metals; cyclopentaclienyl ligands; lanthanides; nitrogen fixation; reduction;

D O I：

10.1002/anie.200461170

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dinitrogen reduction with diamagnetic trivalent lanthanum complexes is possible for the first time using a combination of a trivalent metallocene and potassium graphite. Both [(C5Me4H)3La] and [(C5Me5)2La][BPh4] are viable starting materials and reduce dinitrogen in the presence of KC8 to give [N=N]2- containing structures (see picture).

引用

页码：5517 / 5519

页数：3

共 30 条

[1] Bochkarev M. N., 1997, ANGEW CHEM, V109, P123
[2] Synthesis and structure of the first molecular thulium(II) complex: [TmI2(MeOCH(2)CH(2)OMe)(3)]
Bochkarev, MN
Fedushkin, IL
Fagin, AA
Petrovskaya, TV
Ziller, JW
BroomhallDillard, RNR
Evans, WJ
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (1-2): : 133 - 135
[3] PREPARATION OF YB[N(SIME3)2]2[AIME3]2 - A COMPLEX WITH 4 YB-ME-AL INTERACTIONS
BONCELLA, JM
ANDERSEN, RA
[J]. ORGANOMETALLICS, 1985, 4 (01) : 205 - 206
[4] LOW COORDINATION NUMBERS IN LANTHANIDE AND ACTINIDE COMPOUNDS .1. PREPARATION AND CHARACTERIZATION OF TRIS[BIS(TRIMETHYLSILYL)-AMIDO]LANTHANIDES
BRADLEY, DC
GHOTRA, JS
HART, FA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1973, (10): : 1021 - 1027
[5] The fixation and reduction of dinitrogen using lanthanides: praseodymium and neodymium meso-octaethylporphyrinogen-dinitrogen complexes
Campazzi, E
Solari, E
Floriani, C
Scopelliti, R
[J]. CHEMICAL COMMUNICATIONS, 1998, (23) : 2603 - 2604
[6] Synthesis and characterization of organolanthanidocene(III) (Ln = La, Ce, Pr, Nd) complexes containing the 1,4-cyclohexa-2,5-dienyl ligand (benzene 1,4-dianion):: Structures of [K([18]-crown-6)][Ln{η5-C5H3(SiMe3)2-1,3}2(C6H6)] [Cp" = η5-C5H3(SiMe3)2-1,3; Ln = La, Ce, Nd]
Cassani, MC
Gun'ko, YK
Hitchcock, PB
Lappert, MF
Laschi, F
[J]. ORGANOMETALLICS, 1999, 18 (26) : 5539 - 5547
[7] Cassani MC, 1997, CHEM COMMUN, P1563
[8] Cassani MC, 2002, J ORGANOMET CHEM, V647, P71
[9] Tetrametallic divalent samarium cluster hydride and dinitrogen complexes
Dubé, T
Ganesan, M
Conoci, S
Gambarotta, S
Yap, GPA
[J]. ORGANOMETALLICS, 2000, 19 (18) : 3716 - 3721
[10] Dinitrogen reduction by Tm(II), Dy(II), and Nd(II) with simple amide and aryloxide ligands
Evans, WJ
Zucchi, G
Ziller, JW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (01) : 10 - 11

← 1 2 3 →