Rotationally resolved high (n>100) Rydberg states of benzene

被引：27

作者：

Neuhauser, R

Neusser, HJ

机构：

[1] Inst. fur Phys. und Theor. Chemie, Tech. Universität München, D-85748 Garching

来源：

CHEMICAL PHYSICS LETTERS | 1996年 / 253卷 / 1-2期

关键词：

D O I：

10.1016/0009-2614(96)00236-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Using sub-Doppler double resonance excitation individual high-n Rydberg states were excited in a polyatomic molecule. Even for a selected J(K) intermediate rovibrational state in benzene, C6D6, several Rydberg series are observed converging to different limits. The pulsed field ionization signal has a decay time that is longer than expected from measured lifetimes of low Rydberg states of benzene and ascribed to l-mixing in the residual electric stray field.

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页码：151 / 157

页数：7

相关论文

共 24 条

[1] DYNAMICS OF VERY HIGH RYDBERG STATES OF AROMATIC-MOLECULES [J].

BAHATT, D ;

EVEN, U ;

LEVINE, RD .

JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (02) :1744-1747

[2] DYNAMICS OF ULTRAHIGH MOLECULAR RYDBERGS IN WEAK ELECTRIC-FIELDS [J].

BIXON, M ;

JORTNER, J .

JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (19) :7466-7472

[3] LIFETIMES OF VERY HIGH RYDBERG STATES OF AROMATIC-MOLECULES [J].

CHUPKA, WA .

JOURNAL OF CHEMICAL PHYSICS, 1993, 99 (08) :5800-5806

[4] FACTORS AFFECTING LIFETIMES AND RESOLUTION OF RYDBERG STATES OBSERVED IN ZERO-ELECTRON-KINETIC-ENERGY SPECTROSCOPY [J].

CHUPKA, WA .

JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (06) :4520-4530

[5] OBSERVATIONS OF MOLECULAR RYDBERG STATE DECAY FOR N=10-200 [J].

EVEN, U ;

LEVINE, RD ;

BERSOHN, R .

JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (13) :3472-3477

[6] 2-COLOR MULTIPHOTON IONIZATION SPECTRA OF JET-COOLED PARA-DIFLUOROBENZENE - S AND D RYDBERG STATES [J].

FUJII, M ;

KAKINUMA, T ;

MIKAMI, N ;

ITO, M .

CHEMICAL PHYSICS LETTERS, 1986, 127 (04) :297-302

[7] 2-COLOR MULTIPHOTON IONIZATION AND FLUORESCENCE DIP SPECTRA OF DIAZABICYCLO[2.2.2]OCTANE IN A SUPERSONIC FREE JET - RYDBERG STATES (N=5-39) AND AUTOIONIZATION [J].

FUJII, M ;

EBATA, T ;

MIKAMI, N ;

ITO, M .

JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (19) :4265-4271

[8] ABSORPTION SPECTRUM OF NO MOLECULE .9. STRUCTURE OF F COMPLEXES, IONIZATION POTENTIAL OF NO, AND QUADRUPOLE MOMENT OF NO+ [J].

JUNGEN, C ;

MIESCHER, E .

CANADIAN JOURNAL OF PHYSICS, 1969, 47 (17) :1769-&

[9] DISSOCIATION OF STATE-SELECTED COMPLEX-IONS STUDIED BY MASS-SELECTIVE PULSED FIELD THRESHOLD IONIZATION SPECTROSCOPY [J].

KRAUSE, H ;

NEUSSER, HJ .

JOURNAL OF CHEMICAL PHYSICS, 1992, 97 (08) :5923-5926

[10] DISSOCIATION-ENERGY OF NEUTRAL AND IONIC BENZENE-NOBLE GAS DIMERS BY PULSED-FIELD THRESHOLD IONIZATION SPECTROSCOPY [J].

KRAUSE, H ;

NEUSSER, HJ .

JOURNAL OF CHEMICAL PHYSICS, 1993, 99 (09) :6278-6286