Topology of the distribution of zeros of the Husimi function in the LiNC/LiCN molecular system

被引:11
作者
Arranz, FJ [1 ]
Benito, RM
Borondo, F
机构
[1] Univ Politecn Madrid, ETSI Agron, Dept Fis & Mecan, E-28040 Madrid, Spain
[2] Univ Autonoma Madrid, Dept Quim, E-28049 Madrid, Spain
关键词
D O I
10.1063/1.1665984
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Phase space representations of quantum mechanics constitute useful tools to study vibrations in molecular systems. Among all possibilities, the Husimi function or coherent state representation is very widely used, its maxima indicating which regions of phase space are relevant in the dynamics of the system. The corresponding zeros are also a good indicator to investigate the characteristics of the eigenstates, and it has been shown how the corresponding distributions can discriminate between regular, irregular, and scarred wave functions. In this paper, we discuss how this result can be understood in terms of the overlap between coherent states and system eigenfunctions. (C) 2004 American Institute of Physics.
引用
收藏
页码:6516 / 6523
页数:8
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