2,2′-Biphenol-1,4-diazabicyclo[2.2.2]octane (2/1), a three-dimensional framework built from O-H•••O, O•••N, N-H•••O and C-H•••π(arene) hydrogen bonds

被引：7

作者：

Glidewell, C ^{[1
]}

Ferguson, G

Gregson, RM

Lough, AJ

机构：

[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

[2] Univ Toronto, Lash Miller Chem Labs, Toronto, ON M5S 3H6, Canada

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷

关键词：

D O I：

10.1107/S0108270199011440

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the 2:1 adduct of 2,2'-biphenol and 1,4-diazabicyclo[2.2.2]octane, 2C(12)H(10)O(2). C6H12N2, there are eight molecules of the biphenol and four molecules of the amine in the asymmetric unit, and several of these components exhibit orientational disorder even at 100 K. Each biphenol unit contains an intramolecular O-H ... O hydrogen bond [O ... O range for the ordered components 2.594(6) to 2.668(5) Angstrom]. Each of the amines is hydrogen bonded to two biphenol units [O ... N range for the ordered components 2.521(7) to 2.594(6) Angstrom], so forming four independent three-molecule aggregates. These aggregates are further linked by an extensive series of C-H ...pi(arene) interactions into a continuous three-dimensional framework.

引用

页码：2136 / 2140

页数：5

共 29 条

[1] CRYSTAL-CHEMISTRY OF TETRARADIAL SPECIES .4. HYDROGEN-BONDING TO AROMATIC PI-SYSTEMS - CRYSTAL-STRUCTURES OF 15 TETRAPHENYLBORATES WITH ORGANIC AMMONIUM CATIONS [J].

BAKSHI, PK ;

LINDEN, A ;

VINCENT, BR ;

ROE, SP ;

ADHIKESAVALU, D ;

CAMERON, TS ;

KNOP, O .

CANADIAN JOURNAL OF CHEMISTRY, 1994, 72 (05) :1273-1293

[2]

BOCK H, 1997, J PRAKT CHEM, V26, P339

[3] HYDROGEN-BONDING IN ORGANOMETALLIC CRYSTALS .2. C-H-CENTER-DOT-CENTER-DOT-CENTER-DOT-O HYDROGEN-BONDS IN BRIDGED AND TERMINAL FIRST-ROW METAL-CARBONYLS [J].

BRAGA, D ;

GREPIONI, F ;

BIRADHA, K ;

PEDIREDDI, VR ;

DESIRAJU, GR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (11) :3156-3166

[4] TOWARDS A GRAMMAR OF CRYSTAL PACKING [J].

BROCK, CP ;

DUNITZ, JD .

CHEMISTRY OF MATERIALS, 1994, 6 (08) :1118-1127

[5] 2,2'-Biphenol [J].

Byrne, JJ ;

Chavant, PY ;

Averbuch-Pouchot, MT ;

Vallee, Y .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1998, 54 :1154-1156

[6] 2,2'-biphenol monohydrate [J].

Chen, XM ;

Luo, GB ;

Tong, ML ;

Zhou, ZY .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 :1727-1729

[7] Formation of one-dimensional chains, two-dimensional bilayers and a three-dimensional diamondoid architecture in hydrogen-bonded adducts of 4,4′-biphenol with 1,4-diazabicyclo[2.2.2]octane and 1,2-diaminoethane [J].

Ferguson, G ;

Glidewell, C ;

Gregson, RM ;

Meehan, PR ;

Patterson, ILJ .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1998, 54 :151-161

[8] Crystal engineering using trisphenols. Three-dimensional hydrogen-bonding networks in 1,1,1-tris(4-hydroxyphenyl)ethane, its hydrated adduct with 1,4-diazabicyclo[2.2.2]octane(1/1/1) and its adduct with piperazine(4/3) [J].

Ferguson, G ;

Bell, W ;

Coupar, PI ;

Glidewell, C .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1997, 53 :534-543

[9] Crystal engineering using bisphenols. Chains, ladders and sheets formed by the adducts of 1,4-diazabicyclo[2.2.2]octane with bisphenols: Structures of adducts with 4,4'-isopropylidenediphenol(1/1), 4,4'-oxodiphenol(1/1) and 4,4'-thiodiphenol(1/1 and 2/1) [J].

Ferguson, G ;

Coupar, PI ;

Glidewell, C .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1997, 53 :513-520

[10]

FERGUSON G, 1999, PRPKAPPA WORDPERFECT

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