Parallel modes of C-H bond activation initiated by Cp*Mo(NO)(CH2CMe3)(C6H5) at ambient temperatures

被引：34

作者：

Wada, K ^{[1
]}

Pamplin, CB ^{[1
]}

Legzdins, P ^{[1
]}

机构：

[1] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z1, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 33期

关键词：

D O I：

10.1021/ja027080m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The molybdenum nitrosyl complex Cp*Mo(NO)(CH2CMe3)(C6H5) reacts at room temperature via elimination of neopentane or benzene to form the transient species Cp*Mo(NO)(=CHCMe3) and Cp*Mo(NO)(η2-C6H4). These reactive intermediates effect the intermolecular activation of hydrocarbon C-H bonds via the reverse of the transformations by which they are generated. Thermolysis of Cp*Mo(NO)(CH2CMe3)(C6H5) in pyridine yields the adducts Cp*Mo(NO)(CHCMe3)(NC5H5) and Cp*Mo(NO)(η2-C6H4)(NC5H5), and the benzyne complex has been characterized by X-ray diffraction. Copyright © 2002 American Chemical Society.

引用

页码：9680 / 9681

页数：2

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