Epoxidation of olefins with sodium hypochloride catalysed by new Nickel(II)-Schiff base complexes

被引：27

作者：

Chatterjee, D ^{[1
]}

Mukherjee, S ^{[1
]}

Mitra, A ^{[1
]}

机构：

[1] Cent Mech Engn Res Inst, Chem Sect, Durgapur 713209, India

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2000年 / 154卷 / 1-2期

关键词：

olefin epoxidation; Schiff base Ni(II) complex; hypochloride; homogeneous catalysis; cyclohexene; 1-hexene; stilbenes; indene;

D O I：

10.1016/S1381-1169(99)00293-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

New Schiff-base complexes of Nickel(II), NiL1 (where H2L1 = N,N'-bis(2-hydroxyphenyl)ethylenediimine) and NiL2 (where H2L2 = N-((2-hydroxyphenyl)acetylaldimine)-N'-(2-hydroxyphenyl)acetamide) have been prepared in good yield by direct interaction of 2-aminophenol, glyoxal/methylacetatotate and NiCl2 and characterised by physico-chemical analysis. Catalytic ability of Nit complex were examined and found that both the complexes can effectively catalyse the epoxidation of olefins viz. cyclohexene, l-hexene, cis- and trans-stilbenes, indene with NaOCl. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：5 / 8

页数：4

共 8 条

[1] ELECTROOXIDATIVE POLYMERIZATION OF COBALT, NICKEL AND MANGANESE SALEN COMPLEXES IN ACETONITRILE SOLUTION [J].

BEDIOUI, F ;

LABBE, E ;

GUTIERREZGRANADOS, S ;

DEVYNCK, J .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1991, 301 (1-2) :267-274

[2]

CHATTERJEE A, 1995, NEUROREHABILITATION, V5, P115, DOI 10.3233/NRE-1995-5203

[3] Selective air oxidation of dimethyl sulfide to dimethyl sulfoxide catalysed by aminopolycarboxylatoruthenium(III) complex [J].

Chatterjee, D .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1997, 127 (1-3) :57-60

[4] CATALYSIS OF ALKENE HYDROGENATION AND OXIDATION BY NICKEL SALOPH COMPLEX - A NOVEL BIFUNCTIONAL CATALYST [J].

CHATTERJEE, D ;

BAJAJ, HC ;

HALLIGUDI, SB ;

BHATT, KN .

JOURNAL OF MOLECULAR CATALYSIS, 1993, 84 (01) :L1-L5

[5]

CHATTERJEE D, 1998, IN PRESS J MOL CATAL

[6] ALKENE EPOXIDATION USING NI(II) COMPLEXES OF CHIRAL CYCLAMS [J].

KINNEARY, JF ;

WAGLER, TR ;

BURROWS, CJ .

TETRAHEDRON LETTERS, 1988, 29 (08) :877-880

[7] NICKEL CATALYSIS OF OLEFIN EPOXIDATION [J].

KOOLA, JD ;

KOCHI, JK .

INORGANIC CHEMISTRY, 1987, 26 (06) :908-916

[8] CATALYSIS OF ALKENE OXIDATION BY NICKEL SALEN COMPLEXES USING NAOCL UNDER PHASE-TRANSFER CONDITIONS [J].

YOON, H ;

BURROWS, CJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (12) :4087-4089

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