Molecular design of a wide-band-gap conjugated polymer for efficient fullerene-free polymer solar cells

被引:184
作者
Liu, Delong [1 ,2 ]
Yang, Bei [1 ,2 ]
Jang, Bomee [3 ]
Xu, Bowei [1 ]
Zhang, Shaoqing [1 ]
He, Chang [1 ]
Woo, Han Young [3 ]
Hou, Jianhui [1 ,2 ]
机构
[1] Chinese Acad Sci, State Key Lab Polymer Phys & Chem, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Korea Univ, Dept Chem, Coll Sci, Seoul 136713, South Korea
基金
中国国家自然科学基金; 新加坡国家研究基金会;
关键词
ELECTRON-ACCEPTORS; PHOTOVOLTAIC MATERIALS; ORGANIC PHOTOVOLTAICS; DONOR; SEPARATION; WEIGHT;
D O I
10.1039/c6ee03489f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two p-type conjugated polymers with disparate optical and electronic properties, PB3T and PB2T, were developed and applied in fullerenefree polymer solar cells (PSCs). The photovoltaic performance of the PB3T-based PSC device processed by anisole achieved a high power conversion efficiency of 11.9% with a Jsc of 18.8 mA cm (-2) and V-oc of 1.00 V.
引用
收藏
页码:546 / 551
页数:6
相关论文
共 34 条
[1]   Non-Fullerene Polymer Solar Cells Based on Alkylthio and Fluorine Substituted 2D-Conjugated Polymers Reach 9.5% Efficiency [J].
Bin, Haijun ;
Zhang, Zhi-Guo ;
Gao, Liang ;
Chen, Shanshan ;
Zhong, Lian ;
Xue, Lingwei ;
Yang, Changduk ;
Li, Yongfang .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (13) :4657-4664
[2]   8.4% efficient fullerene-free organic solar cells exploiting long-range exciton energy transfer [J].
Cnops, Kjell ;
Rand, Barry P. ;
Cheyns, David ;
Verreet, Bregt ;
Empl, Max A. ;
Heremans, Paul .
NATURE COMMUNICATIONS, 2014, 5
[3]   A Narrow Optical Gap Small Molecule Acceptor for Organic Solar Cells [J].
Fang, Yuan ;
Pandey, Ajay K. ;
Nardes, Alexandre M. ;
Kopidakis, Nikos ;
Burn, Paul L. ;
Meredith, Paul .
ADVANCED ENERGY MATERIALS, 2013, 3 (01) :54-59
[4]   All-Polymer Solar Cells Based on Absorption-Complementary Polymer Donor and Acceptor with High Power Conversion Efficiency of 8.27% [J].
Gao, Liang ;
Zhang, Zhi-Guo ;
Xue, Lingwei ;
Min, Jie ;
Zhang, Jianqi ;
Wei, Zhixiang ;
Li, Yongfang .
ADVANCED MATERIALS, 2016, 28 (09) :1884-1890
[5]   High-efficiency and air-stable P3HT-based polymer solar cells with a new non-fullerene acceptor [J].
Holliday, Sarah ;
Ashraf, Raja Shahid ;
Wadsworth, Andrew ;
Baran, Derya ;
Yousaf, Syeda Amber ;
Nielsen, Christian B. ;
Tan, Ching-Hong ;
Dimitrov, Stoichko D. ;
Shang, Zhengrong ;
Gasparini, Nicola ;
Alamoudi, Maha ;
Laquai, Frederic ;
Brabec, Christoph J. ;
Salleo, Alberto ;
Durrant, James R. ;
McCulloch, Iain .
NATURE COMMUNICATIONS, 2016, 7
[6]   Bandgap and molecular energy level control. of conjugated polymer photovoltaic materials based on benzo[1,2-b: 4,5-b']dithiophene [J].
Hou, Jianhui ;
Park, Mi-Hyae ;
Zhang, Shaoqing ;
Yao, Yan ;
Chen, Li-Min ;
Li, Juo-Hao ;
Yang, Yang .
MACROMOLECULES, 2008, 41 (16) :6012-6018
[7]   Novel electroluminescent conjugated polyelectrolytes based on polyfluorene [J].
Huang, F ;
Wu, HB ;
Wang, D ;
Yang, W ;
Cao, Y .
CHEMISTRY OF MATERIALS, 2004, 16 (04) :708-716
[8]   Water/alcohol soluble conjugated polymers as highly efficient electron transporting/injection layer in optoelectronic devices [J].
Huang, Fei ;
Wu, Hongbin ;
Cao, Yong .
CHEMICAL SOCIETY REVIEWS, 2010, 39 (07) :2500-2521
[9]   Nonfullerene Polymer Solar Cells with 8.5% Efficiency Enabled by a New Highly Twisted Electron Acceptor Dimer [J].
Hwang, Ye-Jin ;
Li, Haiyan ;
Courtright, Brett A. E. ;
Subramaniyan, Selvam ;
Jenekhe, Samson A. .
ADVANCED MATERIALS, 2016, 28 (01) :124-+
[10]   Low-Bandgap Small Molecules as Non-Fullerene Electron Acceptors Composed of Benzothiadiazole and Diketopyrrolopyrrole for All Organic Solar Cells [J].
Jung, Jae Woong ;
Jo, Won Ho .
CHEMISTRY OF MATERIALS, 2015, 27 (17) :6038-6043