Reaction of the Ruppert-Prakash reagent with perfluorosulfonic acids

被引：23

作者：

Levin, Vitalij V. ^{[1
]}

Dilman, Alexander D. ^{[1
]}

Belyakov, Pavel A. ^{[1
]}

Struchkova, Marina I. ^{[1
]}

Tartakovsky, Vladimir A. ^{[1
]}

机构：

[1] ND Zelinskii Inst Organ Chem, Moscow 119991, Russia

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2009年 / 130卷 / 07期

基金：

俄罗斯基础研究基金会;

关键词：

Trifluoromethyltrimethylsilane; Perfluorosulfonic acids; C-F bond activation; ELECTROPHILIC DIFLUOROMETHYLATING REAGENT; NUCLEOPHILIC TRIFLUOROMETHYLATION; BOND ACTIVATION; TRIFLATE; CHEMISTRY; TRIFLUOROMETHANESULFONATES; BORON; (TRIFLUOROMETHYL)TRIMETHYLSILANE; CARBOCATIONS; GENERATION;

D O I：

10.1016/j.jfluchem.2009.05.003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new property of Me3SiCF3 to undergo C-F bond activation upon interaction with perfluorosulfonic acids is described. The reaction is catalyzed by titanium tetrachloride and affords difluoromethyl perfluorosulfonates in good yields. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：667 / 670

页数：4

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