A {Co32} Nanosphere Supported by p-tert-Butylthiacalix[4]arene

被引：254

作者：

Bi, Yanfeng ^{[1
,3
]}

Wang, Xiu-Teng ^{[2
]}

Liao, Wuping ^{[1
]}

Wang, Xiaofei ^{[1
,3
]}

Wang, Xinwu ^{[1
]}

Zhang, Hongjie ^{[1
]}

Gao, Song ^{[2
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China

[2] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China

[3] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 33期

关键词：

SINGLE-MOLECULE MAGNETS; CLUSTER COMPLEXES; TRANSITION-METAL; ANISOTROPY; CHEMISTRY; WHEEL;

D O I：

10.1021/ja9034939

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Calixarene-capped Co-32 clusters are constructed by a sodalite Co-24(II) cage and an encapsulated Co-8(III) cube. The spherical units are arranged into three isomeric structures, two of which are stacked by the bcc lattices and the third of which is assembled by the cubic closest packing of the spherical units.

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页码：11650 / +

页数：3

相关论文

共 26 条

[1] Synthesis of 3d metallic single-molecule magnets [J].

Aromi, Guillem ;

Brechin, Euan K. .

SINGLE-MOLECULE MAGNETS AND RELATED PHENOMENA, 2006, 122 :1-67

[2] A Unique Mn2Gd2 Tetranuclear Compound of p-tert-Butylthiacalix[4]arene [J].

Bi, Yanfeng ;

Li, Yanling ;

Liao, Wuping ;

Zhang, Hongjie ;

Li, Deqian .

INORGANIC CHEMISTRY, 2008, 47 (21) :9733-9735

[3] A unique rare-earth cluster within a calixarene sandwich: Parallels in the chemistry of cyclosiloxanes and calixarenes [J].

Bilyk, A ;

Hall, AK ;

Harrowfield, JM ;

Hosseini, MW ;

Skelton, BW ;

White, AH .

AUSTRALIAN JOURNAL OF CHEMISTRY, 2000, 53 (11-12) :895-898

[4]

Bilyk A, 2000, EUR J INORG CHEM, P823

[5] Molecular spintronics using single-molecule magnets [J].

Bogani, Lapo ;

Wernsdorfer, Wolfgang .

NATURE MATERIALS, 2008, 7 (03) :179-186

[6] Structural studies of heptanuclear cobalt complexes and larger oligomers based on heptanuclear fragments [J].

Brechin, EK ;

Graham, A ;

Parkin, A ;

Parsons, S ;

Seddon, AM ;

Winpenny, REP .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (19) :3242-3252

[7] Synthesis, structural characterisation and preliminary magnetic studies of a tetraicosanuclear cobalt coordination complex [J].

Brechin, EK ;

Harris, SG ;

Harrison, A ;

Parsons, S ;

Whittaker, AG ;

Winpenny, REP .

CHEMICAL COMMUNICATIONS, 1997, (07) :653-654

[8] Structure, magnetism, and theoretical study of a mixed-valence Co3IICo4III heptanuclear wheel:: Lack of SMM behavior despite negative magnetic anisotropy [J].

Chibotaru, Liviu F. ;

Ungur, Liviu ;

Aronica, Christophe ;

Elmoll, Hani ;

Pilet, Guillaume ;

Luneau, Dominique .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (37) :12445-12455

[9] Polynuclear cobalt(II/III) sulfites:: Synthesis, structure, and magnetic properties of the octanuclear cluster (NH4)11(Li⊂[Co4IICo4III(SO3)16(NH3)8])•10H2O encapsulating a lithium cation [J].

Chilas, George I. ;

Stylianou, Marios ;

Kubicki, Maciej ;

Vaimakis, Tiverios ;

Koegerler, Paul ;

Keramidas, Anastasios D. ;

Kabanos, Themistoklis A. .

INORGANIC CHEMISTRY, 2008, 47 (11) :4451-4453

[10] Tetranuclear manganese(II) complexes of thiacalixarene macrocycles with trigonal prismatic six-coordinate geometries: Synthesis, structure, and magnetic properties [J].

Desroches, C ;

Pilet, G ;

Borshch, SA ;

Parola, S ;

Luneau, D .

INORGANIC CHEMISTRY, 2005, 44 (24) :9112-9120