Infrared optical constants for carvone from the mie inversion of aerosol extinction spectra

被引:21
作者
Dohm, MT [1 ]
Potscavage, AM [1 ]
Niedziela, RF [1 ]
机构
[1] De Paul Univ, Dept Chem, Chicago, IL 60614 USA
关键词
D O I
10.1021/jp0365559
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Frequency-dependent, complex refractive indices for carvone in the mid-infrared from 750 to 5000 cm(-1) have been inverted from the Fourier transform extinction spectra of laboratory-generated aerosols recorded at room temperature. The refractive indices obtained in this analysis are in good qualitative agreement with the results of a previous thin-film study of carvone. However, a full quantitative assessment of this agreement cannot be made as tabulated data for the previous study are no longer available. The refractive indices, or optical constants, reported here add to the small number of frequency-dependent refractive index data sets for other organic compounds that are available in the literature. Such data can be used to elucidate the optical properties of a substance, which are of critical importance in the interpretation of remote sensing data and in the evaluation of how atmospheric particulate matter consisting of organic compounds may affect climate change.
引用
收藏
页码:5365 / 5376
页数:12
相关论文
共 71 条
[1]   ABSORPTION OF VISIBLE RADIATION IN ATMOSPHERE CONTAINING MIXTURES OF ABSORBING AND NON-ABSORBING PARTICLES [J].
ACKERMAN, TP ;
TOON, OB .
APPLIED OPTICS, 1981, 20 (20) :3661-3668
[2]   MODIFIED KRAMERS-KRONIG ANALYSIS OF OPTICAL SPECTRA [J].
AHRENKIEL, RK .
JOURNAL OF THE OPTICAL SOCIETY OF AMERICA, 1971, 61 (12) :1651-+
[3]  
*ALDR CHEM CO, 1981, ALDR LIB INFR SPECTR, P265
[4]  
[Anonymous], 1995, Climate change 1994
[5]  
BAUER N, 1959, TECHNIQUES ORGANIC C, P1139
[6]   INFRARED INTENSITIES OF LIQUIDS .12. ACCURATE OPTICAL-CONSTANTS AND MOLAR ABSORPTION-COEFFICIENTS BETWEEN 6225 AND 500 CM-1 OF BENZENE AT 25-DEGREES-C, FROM SPECTRA RECORDED IN SEVERAL LABORATORIES [J].
BERTIE, JE ;
JONES, RN ;
KEEFE, CD .
APPLIED SPECTROSCOPY, 1993, 47 (07) :891-911
[7]   INFRARED INTENSITIES OF LIQUIDS-XI - INFRARED REFRACTIVE-INDEXES FROM 8000 TO 2 CM-1, ABSOLUTE INTEGRATED-INTENSITIES, AND DIPOLE-MOMENT DERIVATIVES OF METHANOL AT 25-DEGREES-C [J].
BERTIE, JE ;
ZHANG, SL ;
EYSEL, HH ;
BALUJA, S ;
AHMED, MK .
APPLIED SPECTROSCOPY, 1993, 47 (08) :1100-1114
[8]   THE REFRACTIVE-INDEX OF COLORLESS LIQUIDS IN THE VISIBLE AND INFRARED - CONTRIBUTIONS FROM THE ABSORPTION OF INFRARED AND ULTRAVIOLET-RADIATION AND THE ELECTRONIC MOLAR POLARIZABILITY BELOW 20500 CM(-1) [J].
BERTIE, JE ;
LAN, Z .
JOURNAL OF CHEMICAL PHYSICS, 1995, 103 (23) :10152-10161
[9]   INFRARED INTENSITIES OF LIQUIDS .13. ACCURATE OPTICAL-CONSTANTS AND MOLAR ABSORPTION-COEFFICIENTS BETWEEN 6500 AND 435 CM(-1) OF TOLUENE AT 25-DEGREES-C, FROM SPECTRA RECORDED IN SEVERAL LABORATORIES [J].
BERTIE, JE ;
JONES, RN ;
APELBLAT, Y ;
KEEFE, CD .
APPLIED SPECTROSCOPY, 1994, 48 (01) :127-143
[10]   INFRARED INTENSITIES OF LIQUIDS .14. ACCURATE OPTICAL-CONSTANTS AND MOLAR ABSORPTION-COEFFICIENTS BETWEEN 4800 AND 450 CM(-1) OF CHLOROBENZENE AT 25-DEGREES-C FROM SPECTRA RECORDED IN SEVERAL LABORATORIES [J].
BERTIE, JE ;
JONES, RN ;
APELBLAT, Y .
APPLIED SPECTROSCOPY, 1994, 48 (01) :144-159