A tripodal sulfur ligand for the selective ruthenium-catalysed hydrogenation of dimethyl oxalate

被引：40

作者：

Boardman, Brian ^{[1
]}

Hanton, Martin J. ^{[1
]}

van Rensburg, Hendrik ^{[1
]}

Tooze, Robert P. ^{[1
]}

机构：

[1] Sasol Technol UK, St Andrews Lab, St Andrews KY11 8FJ, Fife, Scotland

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 21期

关键词：

D O I：

10.1039/b601216g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first example of a catalyst utilising a sulfur-based ligand [MeC(CH2SBu)(3)] for the selective hydrogenation of dimethyl oxalate to methyl glycolate is reported.

引用

页码：2289 / 2291

页数：3

共 32 条

[1] OSMIUM(III) AND OSMIUM(IV) COMPLEXES OF BIDENTATE AND POLYDENTATE THIOETHERS [J].

ALI, R ;

HIGGINS, SJ ;

LEVASON, W .

INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1984, 84 (01) :65-69

[2] Synthesis and spectroscopic characterisation of tritelluroether, triselenoether, and trithioether complexes of Cr(0), Mo(0) and W(0) [J].

Barton, AJ ;

Connolly, J ;

Levason, W ;

Mendia-Jalon, A ;

Orchard, SD ;

Reid, G .

POLYHEDRON, 2000, 19 (11) :1373-1379

[3] Homogeneous catalysis with transition metal complexes containing sulfur ligands [J].

Bayón, JC ;

Claver, C ;

Masdeu-Bultó, AM .

COORDINATION CHEMISTRY REVIEWS, 1999, 193-5 :73-145

[4]

CANT NW, 1994, CATAL REV SCI ENG, V36, P645

[5]

FONG WS, 2004, PEP REV

[6] ANIONIC METAL HYDRIDE CATALYSTS .2. APPLICATION TO THE HYDROGENATION OF KETONES, ALDEHYDES, CARBOXYLIC-ACID ESTERS, AND NITRILES [J].

GREY, RA ;

PEZ, GP ;

WALLO, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (25) :7536-7542

[7] HOMOGENEOUS CATALYTIC-HYDROGENATION OF CARBOXYLIC-ACID ESTERS TO ALCOHOLS [J].

GREY, RA ;

PEZ, GP ;

WALLO, A ;

CORSI, J .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1980, (16) :783-784

[8]

GREY RA, 1980, Patent No. 4232170

[9]

GREY RA, 1984, FUNDAM RES HOMOGENEO, V4, P97

[10]

GREY RA, 1980, PREPR DIV PET CHEM A, V25, P399

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